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Bamford stevens reaction pdf. Request PDF on ResearchGate| Bamford-Stevens reaction| The Bamford-Stevens reaction and the Shapiro reaction share a similar mechanistic pathway. The former uses a base such as Na, NaOMe, LiH. The Bamford–Stevens reaction is the base-catalyzed decomposition of arenesulfonylhydrazones of aldehydes and ketones, leading to the formation of alkenes and/or cyclopropanes. There are several important general reviews in this area of organic synthesis. Bamford-Stevens Reaction. Tosylhydrazones give alkenes upon treatment with strong bases. This reaction is performed in two steps, where the intermediate diazo compound may be isolated. The Bamford–Stevens reaction is a chemical reaction whereby treatment of tosylhydrazones with strong base gives alkenes. It is named for the British chemist William Randall Bamford and the Scottish chemist Thomas Stevens Stevens (1900–2000).